| 23 mei 2027 | Villarreal CF – Osasuna | ––– | |
| 9 mei 2027 | Villarreal CF – RC Celta de Vigo | ––– | |
| 21 apr 2027 | Villarreal CF – Atlético Madrid | ––– | |
| 11 apr 2027 | Villarreal CF – Athletic Club | ––– | |
| 21 mrt 2027 | Villarreal CF – Málaga CF | ––– | |
| 7 mrt 2027 | Villarreal CF – Real Madrid Club de Fútbol | ––– | |
| 21 feb 2027 | Villarreal CF – Valencia | ––– | |
| 14 feb 2027 | Villarreal CF – FC Barcelona | ––– | |
| 31 jan 2027 | Villarreal CF – Racing Santander | ––– | |
| 17 jan 2027 | Villarreal CF – Deportivo Alavés | ––– | |
| 3 jan 2027 | Villarreal CF – Sevilla FC | ––– | |
| 13 dec 2026 | Villarreal CF – Rayo Vallecano | ––– | |
| 6 dec 2026 | Villarreal CF – Real Sociedad | ––– | |
| 8 nov 2026 | Villarreal CF – Getafe CF | ––– | |
| 1 nov 2026 | Villarreal CF – Espanyol | ––– | |
| 18 okt 2026 | Villarreal CF – Elche CF | ––– | |
| 20 sep 2026 | Villarreal CF – Levante FC | ––– | |
| 13 sep 2026 | Villarreal CF – Real Betis Balompié | ––– | |
| 5 sep 2026 | Villarreal CF – Deportivo de A Coruña | ––– | |
| 24 mei 2026 | Villarreal CF – Ath Madrid | 5–1 | |
| 13 mei 2026 | Villarreal CF – Sevilla FC | 2–3 | |
| 2 mei 2026 | Villarreal CF – Levante FC | 5–1 | |
| 26 apr 2026 | Villarreal CF – RC Celta de Vigo | 2–1 | |
| 20 mrt 2026 | Villarreal CF – Real Sociedad | 3–1 | |
| 8 mrt 2026 | Villarreal CF – Elche CF | 2–1 | |
| 22 feb 2026 | Villarreal CF – Valencia | 2–1 | |
| 9 feb 2026 | Villarreal CF – Espanol | 4–1 | |
| 24 jan 2026 | Villarreal CF – Real Madrid Club de Fútbol | 0–2 | |
| 20 jan 2026 | Villarreal CF – AFC Ajax | 1–2 | |
| 10 jan 2026 | Villarreal CF – Deportivo Alavés | 3–1 | |